Mathews Journal of Forensic Research

2692-8442

Previous Issues Volume 1, Issue 1 - 2018

Research Article Full-Text  PDF  

Forensic Engineering of Advanced Polymeric Materials. Part VI – Degradation of Polyester-based Materials Obtained by Different Processing Methods – Comparative Studies

Joanna Rydz1,2*, Jennifer Gonzalez Ausejo3 , Marta Musioł1 , Wanda Sikorska1 , Jakub Włodarczyk1 , Henryk Janeczek1 , Alena Šišková4 , Brian Johnston5 , Marek Kowalczuk1,5

1Centre of Polymer and Carbon Materials, Polish Academy of Sciences, 34, M. Curie-Sklodowska St., 41-819 Zabrze, Poland.

2Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9/5799, 845 41 Bratislava, Slovakia.

3Polymers and Advanced Materials Group (PIMA), Universitat Jaume I, Avda. Vicent Sos Baynat s/n, 12071 Castellon, Spain.

4Institute of Material and Machine Mechanics, Slovak Academy of Science, Dúbravská cesta 9/6319, 845 13 Bratislava, Slovakia.

5University of Wolverhampton, Faculty of Science and Engineering, Department of Biology, Chemistry and Forensic Science, Wulfruna Street, Wolverhampton, WV1 1LY, UK.

Corresponding Author: Joanna Rydz, Centre of Polymer and Carbon Materials, Polish Academy of Sciences, 34, M. CurieSklodowska St., 41-819 Zabrze, Poland, Tel: +48 32 2716077; E-Mail: [email protected]

Received Date:   02 Mar 2018  
Accepted Date:   30 Apr 2018  
Published Date: 04 May 2018

Copyright © 2018 Joanna Rydz

Citation: Rydz J, Gonzalez Ausejo J, Musioł M, Sikorska W, et al. (2018). Forensic Engineering of Advanced Polymeric Materials. Part VI – Degradation of Polyester-based Materials Obtained by Different Processing Methods – Comparative Studies. Mathews J Foren. 1(1): 003.

 

ABSTRACT

Both ex-ante investigations as well as ex-post studies are needed in the area of advanced polymer materials, particularly (bio) degradable polymers, in order to increase efficiency and to define and minimise the potential failure of novel polymer products before and during specific applications. The after-use properties of such materials are also important and therefore in this study, the degradation of polylactide (PLA) films with different thickness and PLA-based films with poly[(R,S)-3-hydroxybutyrate] ((R,S)-PHB), both obtained by extrusion as well as samples of PLA and its blend with polyhydroxyalkanoate (PHA) obtained by 3D printing with different patterns (printing directions) were investigated. The materials were characterised by optical microscopy, gel permeation chromatography and differential scanning calorimetry analysis. The main aspect of this research is to elaborate on new strategies for the comprehensive characterisation of complex polymer systems obtained by different methods. Comparative studies have allowed conclusions to be drawn from research on various materials under similar conditions.

KEYWORDS

Rigid Film; Filament; Extrusion; Three-Dimensional Printing; Degradation; (Bio)degradable Polyester; PLA; PHA.


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